It currently doesn't do multi-master or automatic DDL. I think DDL should be relatively easy if somebody finishes the deparse extension as the infrastructure for replicating arbitrary commands is present in this patch.
I wish could find the time to get back to this patch. I didn't check it in quite a while...
This is prone to errors when connstring is specified in URI format. A workaround is provided in this commit for walreceiver: b3fc6727ce54a16ae9227bcccfebfa028ac5b16f