I have found that !~ and !~* do not match the null string even when one
would expect them to.  I am not sure if this is how it is supposed to
work or if this is an error.  If this is how it works, I can't figure
out where it is states in the documentation.
Let me give an example.  Suppose we have a table "t" that look as follows:
# SELECT * FROM t;
 n | s
---+---
 1 | a
 2 | b
 3 |
 4 | d
(4 rows)
Now consider the following query results:
# SELECT * FROM t where s ~* 'a';
 n | s
---+---
 1 | a
(1 row)
This works as expected (by me).
# SELECT * FROM t where s !~* 'a';
 n | s
---+---
 2 | b
 4 | d
(2 rows)
This is not what I would have expected.  Instead, I thought the result
would be:
# SELECT * FROM t where s !~* 'a';  --- This does not happen!!
 n | s
---+---
 2 | b
 3 |
 4 | d
(3 rows)
It seems to me that !~* should just be the inverse of ~*, but this does
not seem to be the case.
David