For proc die, it looks like the suggestion was to process it immediately and upon next restart, don't allow user connections unless all sync standbys were caught up. However, we need to be able to allow replication connections from standbys so that they'll be able to stream the needed WAL and catch up with primary, allow superuser or users with pg_monitor role to connect to perform ALTER SYSTEM to remove the unresponsive sync standbys if any from the list or disable sync replication altogether or monitor for flush lsn/catch up status. And block all other connections. Note that replication, superuser and users with pg_monitor role connections are allowed only after the server reaches a consistent state not before that to not read any inconsistent data.
Allowing replication, superuser and pg_monitor seems reasonable to me.
The trickiest part of doing the above is how we detect upon restart that the server received proc die while waiting for sync replication ACK. One idea might be to set a flag in the control file before the crash. Second idea might be to write a marker file (although I don't favor this idea); presence indicates that the server was waiting for sync replication ACK before the crash. However, we may not detect all sorts of crashes in a backend when it is waiting for sync replication ACK to do any of these two ideas. Therefore, this may not be a complete solution.
You cannot control the crash, it can be a simple power failure too and none of them could have reached the disk.
Additionally, this is in a critical transaction commit path.
Third idea might be to just let the primary wait for sync standbys to catch up upon restart irrespective of whether it was crashed or not while waiting for sync replication ACK. While this idea works well without having to detect all sorts of crashes, the primary may not come up if any unresponsive standbys are present (currently, the primary continues to be operational for read-only queries at least irrespective of whether sync standbys have caught up or not).
I prefer this approach because depending on the quorum policy defined in the synchrnous_standby_names, the primary will open connections for read/writes.
If there is no progress from sync standbys then Postgres admin has to jump in regardless.